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膜分离 5

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Preparation and characterization of poly (vinylidene fluoride)/TiO

Weiying LI, Xiuli SUN, Chen WEN, Hui LU, Zhiwei WANG

《环境科学与工程前沿(英文)》 2013年 第7卷 第4期   页码 492-502 doi: 10.1007/s11783-012-0407-x

摘要: Poly(vinylidene fluoride) (PVDF)/titanium dioxide (TiO ) hybrid membranes were prepared using nano-TiO as the modifier, and characterized by Transmission Electron Microscope (TEM), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), atomic force microscope (AFM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The characterization results demonstrated that nano-sized TiO particles dispersed homogeneously within the PVDF matrix, contributing to more hydroxyls and smoother surfaces. Moreover, permeate flux, retention factor, porosity, contact angle and anti-fouling tests were carried out to evaluate the effect of TiO concentration on the performance of PVDF membranes. Among all the prepared membranes, PVDF/TiO membrane containing 10 vol.% TiO exhibited the best hydrophilicity with an average pure water flux up to 237 L·m ·h , higher than that of unmodified PVDF membranes (155 L·m ·h ). Besides, the bovine serum albumin rejection of the hybrid membrane was improved evidently from 52.3% to 70.6%, and the contact angle was significantly lowered from 83° to 60°, while the average pore size and its distribution became smaller and narrower.

关键词: poly(vinylidene fluoride) (PVDF) membrane     nano-TiO2     anti-fouling performance     water treatment    

Poly(vinylidene fluoride--hexafluoro propylene) membranes prepared via thermally induced phase separationand application in direct contact membrane distillation

《化学科学与工程前沿(英文)》 2022年 第16卷 第5期   页码 720-730 doi: 10.1007/s11705-021-2098-y

摘要: A non-toxic and environmentally safe diluent, acetyl tributyl citrate, was employed to prepare poly(vinylidene fluoride)-co-hexafluoropropylene membranes via thermally induced phase separation. Effects of the polymer concentration on the phase diagram, membrane morphology, hydrophobicity, pore size, porosity and mechanical properties (tensile stress and elongation at break) were investigated. The results showed that the pore size and porosity tended to decrease with increasing polymer concentration, whereas the contact angle, liquid entry pressure and mechanical properties showed the opposite trend. In direct contact membrane distillation operation with 3.5 wt-% sodium chloride solution as the feed solution, the prepared membranes performed high salt rejection (>99.9%). Furthermore, the prepared membranes retained excellent performance in long-term stability tests regarding the permeate flux and salt rejection.

关键词: poly(vinylidene fluoride)-co-hexafluoropropylene     thermally induced phase separation     non-toxic diluent     direct contact membrane distillation    

Preparation and characterization of PVDF-PFSA flat sheet ultrafiltration membranes

Jiquan MA, Junhong ZHAO, Zhongbin REN, Lei LI

《化学科学与工程前沿(英文)》 2012年 第6卷 第3期   页码 301-310 doi: 10.1007/s11705-012-1204-6

摘要: High performance polyvinylidene fluoride (PVDF) flat sheet ultrafiltration (UF) membranes have been prepared by an immersion precipitation phase inversion method using perfluorosulfonic acid (PFSA) as a pore former and as a hydrophilic component of the membranes and polyethylene glycol ( = 400) (PEG400) as a pore forming agent. The effects of the presence of PEG and the concentration of the PFSA on the phase separation of the casting solutions and on the morphologies and performance of UF membranes including their porosity, water flux, rejection of bovine serum albumin (BSA) protein, and anti-fouling property were investigated. Phase diagrams, viscosities and the phase separations upon exposure to water vapor showed that both PEG400 and PFSA promoted demixing of the casting solution. Scanning electron microscopy measurements showed that the PVDF-PFSA blend membranes had more macropores and finger-like structures than the native PVDF membranes. The PVDF-PFSA membrane (5 wt-% PEG400+ 5 wt-% PFSA) had a pure water flux of 141.7 L/m ·h, a BSA rejection of 90.1% and a relative pure water flux reduction (RFR) of 15.28%. These properties were greatly superior to those of the native PVDF membrane (pure water flux of 5.6 L/m ·h, BSA rejection of 96.3% and RFR of 42.86%).

关键词: polyvinylidene fluoride     perfluorosulfonic acid     polyethylene glycol     flat sheet membrane     ultrafiltration    

高效选择性PVDF中空纤维膜设计及除铯研究 Article

丁士元, 张利兰, 李阳, 候立安

《工程(英文)》 2019年 第5卷 第5期   页码 865-871 doi: 10.1016/j.eng.2019.07.021

摘要:

本研究通过一种简单有效的接枝方法成功制备了亚铁氰化铜/二氧化硅/聚偏氟乙烯(CuFC/SiO2/PVDF)中空纤维膜。PVDF中空纤维膜通过SiO2中间层将CuFC纳米颗粒固定以去除Cs。分别通过扫描电子显微镜和X射线能谱仪分析了改性膜表面形貌和化学组成。3层CuFC和0.5% SiO2负载制备的CuFC/SiO2/PVDF膜具有非常高的膜渗透通量(49 L·m-2·特别地, CuFC/SiO2/PVDF膜在处理含低浓度Cs(100 μg·L–1)的天然地表水和模拟水体时表现出非常优异的去除率因此,CuFC/SiO2/PVDF膜具有处理受Cs污染的放射性废水的工程应用潜力。

关键词: 铯去除     膜改性     亚铁氰化铜     聚偏氟乙烯    

PVDF ultrafiltration membranes of controlled performance via blending PVDF-g-PEGMA copolymer synthesized

Shuai Wang, Tong Li, Chen Chen, Baicang Liu, John C. Crittenden

《环境科学与工程前沿(英文)》 2018年 第12卷 第2期 doi: 10.1007/s11783-017-0980-0

摘要: Polyvinylidene fluoride grafted with poly(ethylene glycol) methyl ether methacrylate (PVDF-g-PEGMA) was synthesized using atomic transfer radical polymerization (ATRP) at different reaction times (9 h, 19 h, and 29 h). The corresponding conversion rates were 10%, 20% and 30%, respectively. PVDF was blended with the copolymer mixture containing PVDF-g-PEGMA, solvent and residual PEGMA under different reaction times. In this study, we explored the effect of the copolymer mixture additives with different synthesis times on cast membrane performance. Increasing the reaction time of PVDF-g-PEGMA causes more PVDF-g-PEGMA and less residual PEGMA to be found in the casting solution. Incremental PVDF-g-PEGMA can dramatically increase the viscosity of the casting solution. An overly high viscosity led to a delayed phase inversion, thus hindering PEGMA segments in PVDF-g-PEGMA from migrating to the membrane surface. However, more residual PEGMA contributed to helping more PEGMA segments migrate to the membrane surface. The pure water fluxes of the blended membrane with reaction times of 9 h, 19 h, and 29 h are 5445 L·m ·h , 1068 L·m ·h and 1179 L·m ·h , respectively, at 0.07 MPa. Delayed phase inversion can form smaller surface pore size distributions, thus decreasing the water flux for the membranes with PVDF-g-PEGMA at 19 h and 29 h. Therefore, we can control the membrane pore size distribution by decreasing the reaction time of PVDF-g-PEGMA to obtain a better flux performance. The membrane with PVDF-g-PEGMA at 19 h exhibits the best foulant rejection and cleaning recovery due to its narrow pore size distribution and high surface oxygen content.

关键词: Polyvinylidene fluoride ultrafiltration membrane     Amphiphilic copolymer     Blended modification     High flux     Atomic transfer radical polymerization    

Effect of protein on PVDF ultrafiltration membrane fouling behavior under different pH conditions: interface

Xudong WANG,Miao ZHOU,Xiaorong MENG,Lei WANG,Danxi HUANG

《环境科学与工程前沿(英文)》 2016年 第10卷 第4期 doi: 10.1007/s11783-016-0855-9

摘要: pH values of the BSA solution significantly impact the process of membrane fouling. Dramatic flux decline is caused by membrane–BSA adhesion force at start of filtration. XDLVO theory shows the polar or Lewis acid–base interaction plays a major role in membrane fouling. To further determine the fouling behavior of bovine serum albumin (BSA) on different hydrophilic PVDF ultrafiltration (UF) membranes over a range of pH values, self-made atomic force microscopy (AFM) colloidal probes were used to detect the adhesion forces of membrane–BSA and BSA–BSA, respectively. Results showed that the membrane–BSA adhesion interaction was stronger than the BSA–BSA adhesion interaction, and the adhesion force between BSA–BSA-fouled PVDF/PVA membranes was similar to that between BSA–BSA-fouled PVDF/PVP membranes, which indicated that the fouling was mainly caused by the adhesion interaction between membrane and BSA. At the same pH condition, the PVDF/PVA membrane–BSA adhesion force was smaller than that of PVDF/PVP membrane–BSA, which illustrated that the more hydrophilic the membrane was, the better antifouling ability it had. The extended Derjaguin–Landau–Verwey–Overbeek (XDLVO) theory predicts that the polar or Lewis acid–base (AB) interaction played a dominant role in the interfacial free energy of membrane–BSA and BSA–BSA that can be affected by pH. For the same membrane, the pH values of a BSA solution can have a significant impact on the process of membrane fouling by changing the AB component of free energy.

关键词: PVDF membrane     Membrane fouling     Adhesion force     Protein     Interfacial free energy    

Hydrophilic modification of poly(aryl sulfone) membrane materials toward highly-efficient environmental

《化学科学与工程前沿(英文)》 2022年 第16卷 第5期   页码 614-633 doi: 10.1007/s11705-021-2115-1

摘要: Poly(aryl sulfone) as a typical membrane material has been widely used due to excellent mechanical, chemical and thermal stability. However, the inherent hydrophobicity of poly(aryl sulfone) based membranes bears with the fouling issue during applications, which makes the membrane tending to adsorb contaminants on the surface so as to result in decreased separation performance and lifetime. In this critical review, we give a comprehensive overview on characterizations of hydrophilic membrane and diverse hydrophilic modification approaches of poly(aryl sulfone) membranes, predominantly including bulky, blending and surface modification technology. The discussions on the different modification methods have been provided in-depth. Besides, focusing on modification methods and performance of modified membranes, the related mechanisms for the performance enhancement are discussed too. At last, the perspectives are provided to guide the future directions to develop novel technology to manipulate the hydrophilicity of poly(aryl sulfone) membranes toward diverse practical and multi-functional applications.

关键词: poly(aryl sulfone)     membrane separations     modification     hydrophilicity     water treatment    

热致相分离法高性能聚偏氟乙烯中空纤维膜先进制备技术及应用

唐元晖,林亚凯,王晓琳

《中国工程科学》 2014年 第16卷 第12期   页码 24-34

摘要: 十年来清华大学化学工程系在先进膜材料制备及应用技术研究上开展了大量工作,以膜材料配方设计、膜材料先进制造、膜组件设计与应用为主线,突破多个技术难题和瓶颈,实现了热致相分离(TIPS)法高性能聚偏氟乙烯(PVDF首先,基于对TIPS法成膜过程的热力学及动力学研究,制备出具有大通量、高强度、亲水性好的PVDF微孔膜;接着,有机结合材料加工和单元操作,形成PVDF中空纤维膜先进制造技术;最后针对不同的工业环境和市政要求

关键词: 热致相分离     聚偏氟乙烯     水处理     膜制备    

Preparation and properties of gel membrane containing porous PVDF-HFP matrix and cross-linked PEG for

ZHANG Mei, CUI Zhenyu, ZHU Baoku, HAN Gaige, XU Youyi, ZHANG Aiqing

《化学科学与工程前沿(英文)》 2008年 第2卷 第1期   页码 89-94 doi: 10.1007/s11705-008-0011-6

摘要: Lithium ion conducting membranes are the key materials for lithium batteries. The lithium ion conducting gel polymer electrolyte membrane (Li-GPEM) based on porous poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) matrix and cross-linked PEG network is prepared by a typical phase inversion process. By immersing the porous PVDF-HFP membrane in liquid electrolyte containing poly(ethylene glycol) diacrylate (PEGDA) and an initiator to absorb the liquid electrolyte at 25°C, and then thermally cross-linking at 60°C, the Li-GPEM is fabricated successfully. The measurements on its weight loss, mechanical and electrochemical properties reveal that the obtained Li-GPEM has better overall performance than the liquid and blend gel systems used as conductive media in lithium batteries. The ionic conductivity of the fabricated Li-GPEM can reach as high as 2.25 × 10 S/cm at 25°C.

关键词: ethylene     PEGDA     inversion     network     initiator    

dimensional lycopodium with hydrophobic nature and interconnected nano-channels into polyvinylidene fluoridemembranes for desalination applications by vacuum membrane distillation

《化学科学与工程前沿(英文)》 2023年 第17卷 第9期   页码 1162-1182 doi: 10.1007/s11705-022-2276-6

摘要: In the present research, for the first time, lycopodium as a novel nanofiller was incorporated into a polyvinylidene fluoride matrix to fabricate lycopodium/polyvinylidene fluoride flat-sheet membrane for desalination applications by vacuum membrane distillation process. The prepared lycopodium/polyvinylidene fluoride membranes and lycopodium were characterized by field emission scanning electron microscopy, X-ray diffraction, Fourier transform infrared, energy dispersive X-ray, and mapping analyses. Water contact angle and liquid entry pressure measurements were also performed. Response surface methodology was applied to optimize membrane structure and performance. The optimized lycopodium/polyvinylidene fluoride membrane exhibits superior performance compared to the neat polyvinylidene fluoride membrane in terms of flux, salt rejection, water contact angle, and hydrophobicity. In vacuum membrane distillation experiments, using a 15000 ppm NaCl solution as a feed at 70 °C, the neat polyvinylidene fluoride membrane, optimum membrane, and agglomerated membrane (with high lycopodium loading) demonstrated 3.80, 25.20, and 14.83 LMH flux and 63.30%, 99.99%, 99.96% salt rejection, respectively. This improvement in flux and salt rejection of the optimized membrane was related to the presence of lycopodium with hydrophobic nature and interconnected nano-channels in membrane structure. It was found that lycopodium, as the most hydrophobic material, effectively influences the membrane performance and structure for membrane distillation applications.

关键词: lycopodium     hydrophobicity     vacuum membrane distillation     desalination    

Solvent-resistant porous membranes using poly(ether−ether ketone): preparation and application

《化学科学与工程前沿(英文)》 2023年 第17卷 第10期   页码 1536-1559 doi: 10.1007/s11705-022-2221-8

摘要: Poly(ether−ether ketone) (PEEK) is a linear aromatic macromolecule, which can form semi-crystalline aggregative status, allowing PEEK materials to have strong environment tolerance and excellent physicochemical properties. PEEK materials have become a promising alternative to fabricate particular membranes used in extreme conditions. In the past few decades, many researches and evolutions have emerged in membrane fabrication with PEEK materials and its applications for treating organic solvents and their mixtures; however, there are little systematic and comprehensive literature to summarize fabrication approaches, compile applications, and elaborate PEEK property-structure relationship. In this review, the main approaches to fabricate PEEK-based membranes are illustrated concretely, including conventional thermal-induced and non-solvent-induced phase separation, and novel chemical-induced crystallization; the representative applications in ultrafiltration, nanofiltration and membrane contactor containing organic solvents are demonstrated systematically. Meanwhile, the mechanism to tune PEEK solubility in solvents, which can be achieved by altering monomers in synthesis processes or changing membrane preparation routes, is deeply analyzed. Moreover, the existing problems and the future prospects are also discussed. This review provides positive guidance for designing and fabricating membranes using PEEK and its derivative materials for task-specific applications in harsh conditions.

关键词: PEEK     phase inversion     solvent-resistant membrane     nanofiltration     membrane contactor    

G-CNTs/PVDF mixed matrix membranes with improved antifouling properties and filtration performance

Xiaoyan Guo, Chunyu Li, Chenghao Li, Tingting Wei, Lin Tong, Huaiqi Shao, Qixing Zhou, Lan Wang, Yuan Liao

《环境科学与工程前沿(英文)》 2019年 第13卷 第6期 doi: 10.1007/s11783-019-1165-9

摘要:

A novel nanocomposite OMWCNT-A-GO was synthesized by conjugating OMWCNT and GO.

The P-OMWCNT-A-GO membrane was fabricated by non-solvent induced phase inversion.

The P-OMWCNT-A-GO exhibits the best water flux, BSA rejection and flux recovery.

It should be due to the enhanced membrane pore size, porosity and hydrophilicity.

关键词: carbon nanotubes     graphene oxide     mixed matrix membrane     nanohybrid     antifouling membrane     membrane hydrophilicity    

Pilot study for the treatment of sodium and fluoride-contaminated groundwater by using high-pressuremembrane systems

Xiaomao WANG,Hongwei YANG,Zhenyu LI,Shaoxia YANG,Yuefeng XIE

《环境科学与工程前沿(英文)》 2015年 第9卷 第1期   页码 155-163 doi: 10.1007/s11783-014-0740-3

摘要: High-pressure membrane process is one of the cost-effective technologies for the treatment of groundwater containing excessive dissolved solids. This paper reports a pilot study in treating a typical groundwater in Huaibei Plain containing excessive sodium, sulfate and fluoride ions. Three membrane systems were set up and two brands of reverse osmosis (RO), four low-pressure RO (LPRO) and one tight nanofiltration (NF) membranes were tested under this pilot study. An apparent recovery rate at about 75% was adopted. Cartridge filtration, in combination with dosing antiscalent, was not sufficient to reduce the fouling potential of the raw water. All RO and LPRO systems (except for the two severely affected by membrane fouling) demonstrated similar rejection ratios of the conductivity (~98.5%), sodium (~98.5%) and fluoride (~99%). Membrane fouling substantially reduced the rejection performance of the fouled membranes. The tight NF membrane also had a good rejection on conductivity (95%), sodium (94%) and fluoride (95%). All membranes rejected sulfate ion almost completely (more than 99%). The electricity consumptions for the RO, LPRO and NF systems were 1.74, 1.10 and 0.72 kWh?m treated water, respectively. The estimated treatment costs by using typical RO, LPRO and tight NF membrane systems were 1.21, 0.98 and 0.96 CNY?m finished water, respectively. A treatment process consisting of either LPRO or tight NF facilities following multi-media filtration was suggested.

关键词: reverse osmosis (RO)     nanofiltration (NF)     water quality standards     sodium     fluoride     cost estimation    

Uncovering the effect of poly(ethylene-co-vinyl alcohol) molecular weight and vinyl alcohol content onmorphology, antifouling, and permeation properties of polysulfone ultrafiltration membrane: thermodynamic

《化学科学与工程前沿(英文)》 2023年 第17卷 第10期   页码 1484-1502 doi: 10.1007/s11705-023-2331-y

摘要: Various hydrophilic poly(ethylene-co-vinyl alcohol) (EVOH) were used herein to precisely control the structure and hydrodynamic properties of polysulfone (PSF) membranes. Particularly, to prepare pristine PSF and PSF/EVOH blends with increasing vinyl alcohol (VOH: 73%, 68%, 56%), the non-solvent-induced phase separation (NIPS) technique was used. Polyethylene glycol was used as a compatibilizer and as a porogen in N,N-dimethylacetamide. Rheological and ultrasonic separation kinetic measurements were also carried out to develop an ultrafiltration membrane mechanism. The extracted membrane properties and filtration capabilities were systematically compared to the proposed mechanism. Accordingly, the addition of EVOH led to an increase in the rheology of the dopes. The resulting membranes exhibited a microporous structure, while the finger-like structures became more evident with increasing VOH content. The PSF/EVOH behavior was changed from immediate to delayed segregation due to a change in the hydrodynamic kinetics. Interestingly, the PSF/EVOH32 membranes showed high hydrophilicity and achieved a pure water permeability of 264 L·m–2·h–1·bar–1, which was higher than that of pure PSF membranes (171 L·m–2·h–1·bar–1). In addition, PSF/EVOH32 rejected bovine serum albumin at a high rate (> 90%) and achieved a significant restoration of permeability. Finally, from the thermodynamic and hydrodynamic results, valuable insights into the selection of hydrophilic copolymers were provided to tailor the membrane structure while improving both the permeability and antifouling performance.

关键词: polysulfone     blend modification     ultrafiltration membrane     formation hydrodynamics     poly(ethylene-co-vinyl alcohol) copolymer    

An antifouling catechol/chitosan-modified polyvinylidene fluoride membrane for sustainable oil-in-water

Shanshan Zhao, Zhu Tao, Liwei Chen, Muqiao Han, Bin Zhao, Xuelin Tian, Liang Wang, Fangang Meng

《环境科学与工程前沿(英文)》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1355-5

摘要: Abstract • Underwater superoleophobic membrane was fabricated by deposition of catechol/chitosan. • The membrane had ultrahigh pure water flux and was stable under harsh pH conditions. • The membrane exhibited remarkable antifouling property in O/W emulsion separation. • The hydration layer on the membrane surface prevented oil droplets adhesion. Low-pressure membrane filtrations are considered as effective technologies for sustainable oil/water separation. However, conventional membranes usually suffer from severe pore clogging and surface fouling, and thus, novel membranes with superior wettability and antifouling features are urgently required. Herein, we report a facile green approach for the development of an underwater superoleophobic microfiltration membrane via one-step oxidant-induced ultrafast co-deposition of naturally available catechol/chitosan on a porous polyvinylidene fluoride (PVDF) substrate. Membrane morphology and surface chemistry were studied using a series of characterization techniques. The as-prepared membrane retained the original pore structure due to the ultrathin and uniform catechol/chitosan coating. It exhibited ultrahigh pure water permeability and robust chemical stability under harsh pH conditions. Moreover, the catechol/chitosan hydrophilic coating on the membrane surface acting as an energetic barrier for oil droplets could minimize oil adhesion on the surface, which endowed the membrane with remarkable antifouling property and reusability in a cyclic oil-in-water (O/W) emulsion separation. The modified membrane exhibited a competitive flux of ~428 L/(m2·h·bar) after three filtration cycles, which was 70% higher than that of the pristine PVDF membrane. These results suggest that the novel underwater superoleophobic membrane can potentially be used for sustainable O/W emulsions separation, and the proposed green facile modification approach can also be applied to other water-remediation materials considering its low cost and simplicity.

关键词: Antifouling     Catechol/chitosan co-deposition     Oil-in-water emulsions separation     Underwater superoleophobic    

标题 作者 时间 类型 操作

Preparation and characterization of poly (vinylidene fluoride)/TiO

Weiying LI, Xiuli SUN, Chen WEN, Hui LU, Zhiwei WANG

期刊论文

Poly(vinylidene fluoride--hexafluoro propylene) membranes prepared via thermally induced phase separationand application in direct contact membrane distillation

期刊论文

Preparation and characterization of PVDF-PFSA flat sheet ultrafiltration membranes

Jiquan MA, Junhong ZHAO, Zhongbin REN, Lei LI

期刊论文

高效选择性PVDF中空纤维膜设计及除铯研究

丁士元, 张利兰, 李阳, 候立安

期刊论文

PVDF ultrafiltration membranes of controlled performance via blending PVDF-g-PEGMA copolymer synthesized

Shuai Wang, Tong Li, Chen Chen, Baicang Liu, John C. Crittenden

期刊论文

Effect of protein on PVDF ultrafiltration membrane fouling behavior under different pH conditions: interface

Xudong WANG,Miao ZHOU,Xiaorong MENG,Lei WANG,Danxi HUANG

期刊论文

Hydrophilic modification of poly(aryl sulfone) membrane materials toward highly-efficient environmental

期刊论文

热致相分离法高性能聚偏氟乙烯中空纤维膜先进制备技术及应用

唐元晖,林亚凯,王晓琳

期刊论文

Preparation and properties of gel membrane containing porous PVDF-HFP matrix and cross-linked PEG for

ZHANG Mei, CUI Zhenyu, ZHU Baoku, HAN Gaige, XU Youyi, ZHANG Aiqing

期刊论文

dimensional lycopodium with hydrophobic nature and interconnected nano-channels into polyvinylidene fluoridemembranes for desalination applications by vacuum membrane distillation

期刊论文

Solvent-resistant porous membranes using poly(ether−ether ketone): preparation and application

期刊论文

G-CNTs/PVDF mixed matrix membranes with improved antifouling properties and filtration performance

Xiaoyan Guo, Chunyu Li, Chenghao Li, Tingting Wei, Lin Tong, Huaiqi Shao, Qixing Zhou, Lan Wang, Yuan Liao

期刊论文

Pilot study for the treatment of sodium and fluoride-contaminated groundwater by using high-pressuremembrane systems

Xiaomao WANG,Hongwei YANG,Zhenyu LI,Shaoxia YANG,Yuefeng XIE

期刊论文

Uncovering the effect of poly(ethylene-co-vinyl alcohol) molecular weight and vinyl alcohol content onmorphology, antifouling, and permeation properties of polysulfone ultrafiltration membrane: thermodynamic

期刊论文

An antifouling catechol/chitosan-modified polyvinylidene fluoride membrane for sustainable oil-in-water

Shanshan Zhao, Zhu Tao, Liwei Chen, Muqiao Han, Bin Zhao, Xuelin Tian, Liang Wang, Fangang Meng

期刊论文